Congratulations Dr. Codillo on a very successful Ph.D. defense! On to a prestigious postdoc scholarship at Carnegie now!
This year, Postodoctoral investigator Rellie Goddard, Andy Cross, and myself have the pleasure to host undergraduate student Namitha Kumar from the University of Michigan as part of the prestigious SSF program at WHOI. Namitha will work on combining geochemical analyses by LA-ICP-MS and electron microprobe with rheological measurements by EBSD on gabbros from the South West Indian Ridge to investigate the strength of the lower oceanic crust. Welcome Namitha!
Magmatic volatiles (for example, water) are abundant in arc melts and exert fundamental controls on magma evolution, eruption dynamics and the formation of economic ore deposits. To constrain the H2O content of arc magmas, most studies have relied on measuring extrusive products and mineral-hosted melt inclusions. However, these methods have inherent limitations that obfuscate the full range of H2O in arc magmas. Here, we report secondary-ion mass spectrometry measurements of volatile (H2O, F, P, S, Cl) abundances in lower-crustal cumulate minerals from the Kohistan palaeo-arc (northwestern Pakistan) and determine H2O abundances of melts from which the cumulates crystallized. Pyroxenes retained magmatic H2O abundances and record damp (less than 1 wt% H2O) to hydrous (up to 10 wt% H2O) primitive melts. Subsequent crystal fractionation led to formation of super-hydrous melts with approximately 12–20 wt% H2O, predicted petrologically yet virtually absent from the melt-inclusion record. Porphyry copper deposits are probably a natural eventuality of fluid exsolution from super-hydrous melts, corroborating a growing body of evidence.
See more press releases here:
The deadline for application to the WHOI postdoctoral program is Oct. 15th 2021, and the deadline for application to the MIT/WHOI Joint Program (PhD) is December 15th. Contact me if you would like to work in The Mantle Rocks lab.
More details on the application process below.
The large range of H2O contents recorded in minerals from exhumed mantle rocks has been challenging to interpret, as it often records a combination of melting, metasomatism, and diffusional processes in spatially isolated samples. Here, we determine the temporal variations of H2O contents in pyroxenes from a 24-Ma time series of abyssal peridotites exposed along the Vema fracture zone (Atlantic Ocean). The H2O contents of pyroxenes correlate with both crustal ages and pyroxene chemistry and increase toward younger and more refractory peridotites. These variations are inconsistent with residual values after melting and opposite to trends often observed in mantle xenoliths. Postmelting hydrogen enrichment occurred by ionic diffusion during cryptic metasomatism of peridotite residues by low-degree, volatile-rich melts and was particularly effective in the most depleted peridotites. The presence of hydrous melts under ridges leads to widespread hydrogen incorporation in the oceanic lithosphere, likely lowering mantle viscosity compared to dry models.
Ben Urann has graduated from the MIT/WHOI Joint Program (2015-2021)! Congratulations for a great job Ben!
I have obtained a visiting Scholar award to visit the IGN, University of Copenhagen (Denmark) for some months. Thank you to both WHOI and IGN for support.
Quantifying the concurrent changes in rock volume and fluid composition during serpentinization remains a major challenge in assessing its physicochemical effects during continental rifting, seafloor spreading, and subduction. Here we conducted a series of 11 hydrothermal laboratory experiments where cylindrical cores of natural dunite, harzburgite, and pyroxenite were reacted with an aqueous solution at 300 °C and 35 MPa for up to 18 months. Using three-dimensional microcomputed tomography and thermogravimetry, we show that rock volume systematically increased with time and extent of reaction, leading to a volume increase of 44% (±8%) in altered rock domains after 10–18 months of serpentinization. The volume expansion was accompanied by Mg-Ca exchange between fluid and rock, while Fe and Si were largely conserved. We find that the protolith composition (olivine/orthopyroxene ratio) plays a significant role in controlling the fluid chemistry and the proportions of hydrous secondary minerals during serpentinization. Agreement between alteration mineralogy, composition of reacting fluids, and measured volume changes suggests that serpentinization under static conditions is a volume-increasing process in spite of demonstrable mass transfer. Volume expansion implies an increased water carrying capacity and buoyancy force of serpentinite per unit mass of protolith, while Mg-Ca exchange during serpentinization may affect the Mg/Ca ratio of seawater on Earth and possibly other ocean worlds.